(2,2′-Bipyridine-κ2 N,N′){N-[2-oxido-5-(phenyldiazenyl)benzylidene-κO]glycinato-κ2 N,O}copper(II)
نویسندگان
چکیده
In the title compound, [Cu(C(15)H(11)N(3)O(3))(C(10)H(8)N(2))], the Cu(II) atom is five-coordinated in a distorted square-pyramidal CuN(3)O(2) geometry. The basal positions are occupied by three donor atoms from the tridentate Schiff base ligand and by one N atom from the 2,2'-bipyridine ligand. The axial position is occupied by the other N atom of the 2,2'-bipyridine ligand. The crystal structure is consolidated by weak C-H⋯O hydrogen bonds. In addition, π-π inter-actions between adjacent pyridine rings (centroid-centroid distances = 3.238 and 3.313 Å) may also stabilize the crystal packing.
منابع مشابه
Diammonium bis[(2-aminoacetato-κ2 N,O)(2,2′-bipyridine-κ2 N,N′)(N,N-dimethylformamide-κO)copper(II)] hexacosaoxidooctamolybdate(VI)
The title compound, (NH(4))(2)[Cu(C(2)H(4)NO(2))(C(10)H(8)N(2))(C(3)H(7)NO)](2)[Mo(8)O(26)], contains a centrosymmetric β-type octa-molybdate anion, two copper(II) complex cations and two ammonium ions. The Cu(II) atom is coordinated in a square-pyramidal geometry by a 2,2'-bipyridine and a 2-amino-acetate ligands in the basal plane and by an O atom of N,N-dimethyl-formamide in the apical posit...
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